Beilstein J. Org. Chem.2017,13, 372–383, doi:10.3762/bjoc.13.40
synergistic combination of optimally arranged functional groups could be identified. The highest possible level of intramolecular synergism was found for low viscous N,N'-diacryloyl-N,N'-diallyl-1,4-but-2-enediamine.
Keywords: acrylamide; allyl; cyclopolymerization; photopolymerization; spatialeffect
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Graphical Abstract
Scheme 1:
Top: Overview of the synthesized crosslinkers 1–6 and their correlation to each other via formal re...